Additions to and Substitutions at C-C &pgr;-Bonds, Volume 4
M.F. Semmelhack
Volume 4 focuses on additions and the resulting substitutions at carbon-carbon &pgr;-bonds. Part 1 includes processes generally considered as simple polar reactions, reactive electrophiles and nucleophiles adding to alkenes and alkynes. A major topic is Michael-type addition to electron deficient &pgr;-bonds, featured in the first six chapters. In part 2 are collected the four general processes leading to nucleophilic aromatic substitution, including radical chain processes and transition metal activation through to &pgr;-complexation. Metal-activated addition (generally by nucleophiles) to alkenes and polyenes is presented in part 3, including allylic alkylation catalyzed by palladium. The coverage of nonpolar additions in part 4 includes radical additions, organometal addition (Heck reaction), carbene addition, and 1,3-dipolar cycloadditions.
Категории:
Том:
vol.4
Год:
1992
Издательство:
Pergamon
Язык:
english
Страницы:
1294
ISBN 10:
0080405959
ISBN 13:
9780080405957
Серия:
Comprehensive Organic Synthesis 4.
Файл:
DJVU, 13.45 MB
IPFS:
,
english, 1992
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